AA 9602 then FR 9602 at Madrid
Philadelphia → Madrid → Rome
Timetable, Madrid time
13:30AA 9602 from Philadelphia at the gate
07:40FR 9602 to Rome leaves the gate
18 h 10 apart on the timetable, overnight
FR 9602 leaves 18 h 10 after AA 9602 arrives on the timetable: more than half a day, so not a connection we count.