AV 14 then EW 9511 at Madrid
Cali → Madrid → Düsseldorf
Timetable, Madrid time
13:55AV 14 from Cali at the gatealso EY 2607, EK 3806, CA 5308
13:10EW 9511 to Düsseldorf leaves the gate
23 h 15 apart on the timetable, overnight
EW 9511 leaves 23 h 15 after AV 14 arrives on the timetable: more than half a day, so not a connection we count.