AV 16 then EW 9511 at Madrid
Medellín → Madrid → Düsseldorf
Timetable, Madrid time
13:55AV 16 from Medellín at the gatealso EY 2608, EK 3804, CA 5310
13:10EW 9511 to Düsseldorf leaves the gate
23 h 15 apart on the timetable, overnight
EW 9511 leaves 23 h 15 after AV 16 arrives on the timetable: more than half a day, so not a connection we count.