AZ 60 then EW 9511 at Madrid
Rome → Madrid → Düsseldorf
Timetable, Madrid time
17:10AZ 60 from Rome at the gate
13:10EW 9511 to Düsseldorf leaves the gate
20 h apart on the timetable, overnight
EW 9511 leaves 20 h after AZ 60 arrives on the timetable: more than half a day, so not a connection we count.