AZ 60 then FR 4066 at Madrid
Rome → Madrid → Catania
Timetable, Madrid time
17:10AZ 60 from Rome at the gate
07:00FR 4066 to Catania leaves the gate
13 h 50 apart on the timetable, overnight
FR 4066 leaves 13 h 50 after AZ 60 arrives on the timetable: more than half a day, so not a connection we count.