AZ 60 then FR 5993 at Madrid
Rome → Madrid → London Stansted
Timetable, Madrid time
17:10AZ 60 from Rome at the gate
13:20FR 5993 to London Stansted leaves the gate
20 h 10 apart on the timetable, overnight
FR 5993 leaves 20 h 10 after AZ 60 arrives on the timetable: more than half a day, so not a connection we count.