BA 462 then FR 2528 at Madrid
London Heathrow → Madrid → Berlin
Timetable, Madrid time
13:40BA 462 from London Heathrow at the gate
05:50FR 2528 to Berlin leaves the gate
16 h 10 apart on the timetable, overnight
FR 2528 leaves 16 h 10 after BA 462 arrives on the timetable: more than half a day, so not a connection we count.