BA 462 then FR 3009 at Madrid
London Heathrow → Madrid → Milan
Timetable, Madrid time
13:35BA 462 from London Heathrow at the gate
09:15FR 3009 to Milan leaves the gate
19 h 40 apart on the timetable, overnight
FR 3009 leaves 19 h 40 after BA 462 arrives on the timetable: more than half a day, so not a connection we count.