CX 1906 then FR 2528 at Madrid
Vigo → Madrid → Berlin
Timetable, Madrid time
07:45CX 1906 from Vigo at the gate
06:15FR 2528 to Berlin leaves the gate
22 h 30 apart on the timetable, overnight
FR 2528 leaves 22 h 30 after CX 1906 arrives on the timetable: more than half a day, so not a connection we count.