DE 9272 then W4 7545 at Madrid
Munich → Madrid → Seville
Timetable, Madrid time
15:00DE 9272 from Munich at the gate
14:35W4 7545 to Seville leaves the gate
23 h 35 apart on the timetable, overnight
W4 7545 leaves 23 h 35 after DE 9272 arrives on the timetable: more than half a day, so not a connection we count.