ES 895 then FR 9602 at Madrid
Caracas → Madrid → Rome
Timetable, Madrid time
11:35ES 895 from Caracas at the gate
09:20FR 9602 to Rome leaves the gate
21 h 45 apart on the timetable, overnight
FR 9602 leaves 21 h 45 after ES 895 arrives on the timetable: more than half a day, so not a connection we count.