ES 895 then W4 7543 at Madrid
Caracas → Madrid → Seville
Timetable, Madrid time
11:35ES 895 from Caracas at the gate
10:20W4 7543 to Seville leaves the gate
22 h 45 apart on the timetable, overnight
W4 7543 leaves 22 h 45 after ES 895 arrives on the timetable: more than half a day, so not a connection we count.