EW 9510 then FR 9674 at Madrid
Düsseldorf → Madrid → Rome
Timetable, Madrid time
17:35EW 9510 from Düsseldorf at the gate
16:00FR 9674 to Rome leaves the gate
22 h 25 apart on the timetable, overnight
FR 9674 leaves 22 h 25 after EW 9510 arrives on the timetable: more than half a day, so not a connection we count.