FR 1063 then FR 4066 at Madrid
Warsaw Modlin → Madrid → Catania
Timetable, Madrid time
21:10FR 1063 from Warsaw Modlin at the gate
09:30FR 4066 to Catania leaves the gate
12 h 20 apart on the timetable, overnight
FR 4066 leaves 12 h 20 after FR 1063 arrives on the timetable: more than half a day, so not a connection we count.