FR 1207 then FR 5321 at Madrid
Venezia → Madrid → Milan
Timetable, Madrid time
19:40FR 1207 from Venezia at the gate
13:20FR 5321 to Milan leaves the gate
17 h 40 apart on the timetable, overnight
FR 5321 leaves 17 h 40 after FR 1207 arrives on the timetable: more than half a day, so not a connection we count.