FR 1207 then PU 701 at Madrid
Venezia → Madrid → Caracas
Timetable, Madrid time
21:50FR 1207 from Venezia at the gate
13:00PU 701 to Caracas leaves the gate
15 h 10 apart on the timetable, overnight
PU 701 leaves 15 h 10 after FR 1207 arrives on the timetable: more than half a day, so not a connection we count.