FR 2210 then FR 348 at Madrid
Venezia → Madrid → London Stansted
Timetable, Madrid time
16:25FR 2210 from Venezia at the gate
14:30FR 348 to London Stansted leaves the gate
22 h 05 apart on the timetable, overnight
FR 348 leaves 22 h 05 after FR 2210 arrives on the timetable: more than half a day, so not a connection we count.