FR 2210 then FR 5997 at Madrid
Venezia → Madrid → London Stansted
Timetable, Madrid time
23:25FR 2210 from Venezia at the gate
18:55FR 5997 to London Stansted leaves the gate
19 h 30 apart on the timetable, overnight
FR 5997 leaves 19 h 30 after FR 2210 arrives on the timetable: more than half a day, so not a connection we count.