FR 2210 then FR 725 at Madrid
Venezia → Madrid → Palermo
Timetable, Madrid time
23:25FR 2210 from Venezia at the gate
21:25FR 725 to Palermo leaves the gate
22 h apart on the timetable, overnight
FR 725 leaves 22 h after FR 2210 arrives on the timetable: more than half a day, so not a connection we count.