FR 2210 then W4 6014 at Madrid
Venezia → Madrid → Rome
Timetable, Madrid time
23:25FR 2210 from Venezia at the gate
20:40W4 6014 to Rome leaves the gate
21 h 15 apart on the timetable, overnight
W4 6014 leaves 21 h 15 after FR 2210 arrives on the timetable: more than half a day, so not a connection we count.