FR 2210 then W4 6314 at Madrid
Venezia → Madrid → Milan
Timetable, Madrid time
23:25FR 2210 from Venezia at the gate
23:10W4 6314 to Milan leaves the gate
23 h 45 apart on the timetable, overnight
W4 6314 leaves 23 h 45 after FR 2210 arrives on the timetable: more than half a day, so not a connection we count.