FR 2527 then BA 465 at Madrid
Berlin → Madrid → London Heathrow
Timetable, Madrid time
23:10FR 2527 from Berlin at the gate
18:10BA 465 to London Heathrow leaves the gate
19 h apart on the timetable, overnight
BA 465 leaves 19 h after FR 2527 arrives on the timetable: more than half a day, so not a connection we count.