FR 2527 then EC 7646 at Madrid
Berlin → Madrid → Lisbon
Timetable, Madrid time
23:10FR 2527 from Berlin at the gate
18:00EC 7646 to Lisbon leaves the gate
18 h 50 apart on the timetable, overnight
EC 7646 leaves 18 h 50 after FR 2527 arrives on the timetable: more than half a day, so not a connection we count.