FR 2752 then FR 607 at Madrid
Milan → Madrid → Copenhagen
Timetable, Madrid time
21:35FR 2752 from Milan at the gate
10:15FR 607 to Copenhagen leaves the gate
12 h 40 apart on the timetable, overnight
FR 607 leaves 12 h 40 after FR 2752 arrives on the timetable: more than half a day, so not a connection we count.