FR 2752 then UX 39 at Madrid
Milan → Madrid → Guayaquil
Timetable, Madrid time
08:05FR 2752 from Milan at the gate
01:45UX 39 to Guayaquil leaves the gate
17 h 40 apart on the timetable, overnight
UX 39 leaves 17 h 40 after FR 2752 arrives on the timetable: more than half a day, so not a connection we count.