FR 2761 then FR 5686 at Madrid
Bari → Madrid → Edinburgh
Timetable, Madrid time
18:45FR 2761 from Bari at the gate
17:25FR 5686 to Edinburgh leaves the gate
22 h 40 apart on the timetable, overnight
FR 5686 leaves 22 h 40 after FR 2761 arrives on the timetable: more than half a day, so not a connection we count.