FR 3008 then A3 4035 at Madrid
Milan → Madrid → Athens
Timetable, Madrid time
19:50FR 3008 from Milan at the gate
13:20A3 4035 to Athens leaves the gate
17 h 30 apart on the timetable, overnight
A3 4035 leaves 17 h 30 after FR 3008 arrives on the timetable: more than half a day, so not a connection we count.