FR 3008 then FR 3186 at Madrid
Milan → Madrid → Manchester
Timetable, Madrid time
11:45FR 3008 from Milan at the gate
06:00FR 3186 to Manchester leaves the gate
18 h 15 apart on the timetable, overnight
FR 3186 leaves 18 h 15 after FR 3008 arrives on the timetable: more than half a day, so not a connection we count.