FR 3008 then SN 3722 at Madrid
Milan → Madrid → Brussels
Timetable, Madrid time
19:50FR 3008 from Milan at the gate
12:35SN 3722 to Brussels leaves the gate
16 h 45 apart on the timetable, overnight
SN 3722 leaves 16 h 45 after FR 3008 arrives on the timetable: more than half a day, so not a connection we count.