FR 3008 then SN 3728 at Madrid
Milan → Madrid → Brussels
Timetable, Madrid time
19:50FR 3008 from Milan at the gate
17:30SN 3728 to Brussels leaves the gate
21 h 40 apart on the timetable, overnight
SN 3728 leaves 21 h 40 after FR 3008 arrives on the timetable: more than half a day, so not a connection we count.