FR 3187 then FR 3814 at Madrid
Manchester → Madrid → Bologna
Timetable, Madrid time
22:25FR 3187 from Manchester at the gate
12:45FR 3814 to Bologna leaves the gate
14 h 20 apart on the timetable, overnight
FR 3814 leaves 14 h 20 after FR 3187 arrives on the timetable: more than half a day, so not a connection we count.