FR 3187 then FR 3831 at Madrid
Manchester → Madrid → Bologna
Timetable, Madrid time
22:25FR 3187 from Manchester at the gate
21:00FR 3831 to Bologna leaves the gate
22 h 35 apart on the timetable, overnight
FR 3831 leaves 22 h 35 after FR 3187 arrives on the timetable: more than half a day, so not a connection we count.