FR 3187 then FR 5995 at Madrid
Manchester → Madrid → London Stansted
Timetable, Madrid time
22:25FR 3187 from Manchester at the gate
18:50FR 5995 to London Stansted leaves the gate
20 h 25 apart on the timetable, overnight
FR 5995 leaves 20 h 25 after FR 3187 arrives on the timetable: more than half a day, so not a connection we count.