FR 347 then FR 9493 at Madrid
London Stansted → Madrid → Pisa
Timetable, Madrid time
09:25FR 347 from London Stansted at the gate
21:45FR 9493 to Pisa leaves the gate
12 h 20 apart on the timetable
FR 9493 leaves 12 h 20 after FR 347 arrives on the timetable: more than half a day, so not a connection we count.