FR 3813 then FR 6815 at Madrid
Bologna → Madrid → Manchester
Timetable, Madrid time
12:10FR 3813 from Bologna at the gate
10:40FR 6815 to Manchester leaves the gate
22 h 30 apart on the timetable, overnight
FR 6815 leaves 22 h 30 after FR 3813 arrives on the timetable: more than half a day, so not a connection we count.