FR 393 then PU 701 at Madrid
Ibiza → Madrid → Caracas
Timetable, Madrid time
16:35FR 393 from Ibiza at the gate
13:00PU 701 to Caracas leaves the gate
20 h 25 apart on the timetable, overnight
PU 701 leaves 20 h 25 after FR 393 arrives on the timetable: more than half a day, so not a connection we count.