FR 403 then FR 4066 at Madrid
Palma de Mallorca → Madrid → Catania
Timetable, Madrid time
23:35FR 403 from Palma de Mallorca at the gate
18:20FR 4066 to Catania leaves the gate
18 h 45 apart on the timetable, overnight
FR 4066 leaves 18 h 45 after FR 403 arrives on the timetable: more than half a day, so not a connection we count.