FR 4065 then FR 3009 at Madrid
Catania → Madrid → Milan
Timetable, Madrid time
00:15FR 4065 from Catania at the gate
14:25FR 3009 to Milan leaves the gate
14 h 10 apart on the timetable
FR 3009 leaves 14 h 10 after FR 4065 arrives on the timetable: more than half a day, so not a connection we count.