FR 4065 then FR 494 at Madrid
Catania → Madrid → Dublin
Timetable, Madrid time
13:10FR 4065 from Catania at the gate
07:50FR 494 to Dublin leaves the gate
18 h 40 apart on the timetable, overnight
FR 494 leaves 18 h 40 after FR 4065 arrives on the timetable: more than half a day, so not a connection we count.