FR 4065 then FR 5323 at Madrid
Catania → Madrid → Milan Bergamo
Timetable, Madrid time
00:15FR 4065 from Catania at the gate
16:40FR 5323 to Milan Bergamo leaves the gate
16 h 25 apart on the timetable
FR 5323 leaves 16 h 25 after FR 4065 arrives on the timetable: more than half a day, so not a connection we count.