FR 4065 then FR 690 at Madrid
Catania → Madrid → Vienna
Timetable, Madrid time
12:15FR 4065 from Catania at the gate
09:45FR 690 to Vienna leaves the gate
21 h 30 apart on the timetable, overnight
FR 690 leaves 21 h 30 after FR 4065 arrives on the timetable: more than half a day, so not a connection we count.