FR 4065 then IB 651 at Madrid
Catania → Madrid → Rome
Timetable, Madrid time
13:10FR 4065 from Catania at the gate
13:05IB 651 to Rome leaves the gate
23 h 55 apart on the timetable, overnight
IB 651 leaves 23 h 55 after FR 4065 arrives on the timetable: more than half a day, so not a connection we count.