FR 5055 then W4 5152 at Madrid
Luxembourg → Madrid → Tirana
Timetable, Madrid time
22:35FR 5055 from Luxembourg at the gate
16:50W4 5152 to Tirana leaves the gate
18 h 15 apart on the timetable, overnight
W4 5152 leaves 18 h 15 after FR 5055 arrives on the timetable: more than half a day, so not a connection we count.