FR 5322 then LX 2033 at Madrid
Milan → Madrid → Zurich
Timetable, Madrid time
19:45FR 5322 from Milan at the gate
19:30LX 2033 to Zurich leaves the gate
23 h 45 apart on the timetable, overnight
LX 2033 leaves 23 h 45 after FR 5322 arrives on the timetable: more than half a day, so not a connection we count.