FR 5377 then FR 2528 at Madrid
Brussels Charleroi → Madrid → Berlin
Timetable, Madrid time
12:20FR 5377 from Brussels Charleroi at the gate
06:40FR 2528 to Berlin leaves the gate
18 h 20 apart on the timetable, overnight
FR 2528 leaves 18 h 20 after FR 5377 arrives on the timetable: more than half a day, so not a connection we count.