FR 5377 then FR 6815 at Madrid
Brussels Charleroi → Madrid → Manchester
Timetable, Madrid time
13:35FR 5377 from Brussels Charleroi at the gate
10:40FR 6815 to Manchester leaves the gate
21 h 05 apart on the timetable, overnight
FR 6815 leaves 21 h 05 after FR 5377 arrives on the timetable: more than half a day, so not a connection we count.