FR 5992 then FR 572 at Madrid
Milan Bergamo → Madrid → Porto
Timetable, Madrid time
08:45FR 5992 from Milan Bergamo at the gate
22:40FR 572 to Porto leaves the gate
13 h 55 apart on the timetable
FR 572 leaves 13 h 55 after FR 5992 arrives on the timetable: more than half a day, so not a connection we count.