FR 606 then IB 191 at Madrid
Copenhagen → Madrid → Caracas
Timetable, Madrid time
13:35FR 606 from Copenhagen at the gate
13:10IB 191 to Caracas leaves the gate
23 h 35 apart on the timetable, overnight
IB 191 leaves 23 h 35 after FR 606 arrives on the timetable: more than half a day, so not a connection we count.