FR 6814 then EW 9511 at Madrid
Manchester → Madrid → Düsseldorf
Timetable, Madrid time
23:55FR 6814 from Manchester at the gate
18:20EW 9511 to Düsseldorf leaves the gate
18 h 25 apart on the timetable, overnight
EW 9511 leaves 18 h 25 after FR 6814 arrives on the timetable: more than half a day, so not a connection we count.