FR 6814 then FR 5315 at Madrid
Manchester → Madrid → Rome
Timetable, Madrid time
23:55FR 6814 from Manchester at the gate
18:05FR 5315 to Rome leaves the gate
18 h 10 apart on the timetable, overnight
FR 5315 leaves 18 h 10 after FR 6814 arrives on the timetable: more than half a day, so not a connection we count.